中国电力 ›› 2019, Vol. 52 ›› Issue (5): 170-175.DOI: 10.11930/j.issn.1004-9649.201808099

• 节能与环保 • 上一篇    下一篇

SCR催化剂的磨损试验与数值模拟研究

闫俊伏, 赵学斌   

  1. 山西兴能发电有限责任公司, 山西 太原 030206
  • 收稿日期:2018-08-20 修回日期:2018-10-20 出版日期:2019-05-05 发布日期:2019-05-14
  • 通讯作者: 赵学斌(1970-),男,通信作者,工学学士,从事低热值高硫煤在对冲超临界锅炉、四角切圆锅炉低氮稳燃研究,E-mail:zxbzylzdy@126.com
  • 作者简介:闫俊伏(1963-),男,高级工程师,从事煤/气混燃锅炉燃烧稳定性研究和SCR催化剂的磨损试验与数值模拟研究,E-mail:yjf8811@126.com;赵学斌(1970-),男,通信作者,从事低热值高硫煤在对冲超临界锅炉、四角切圆锅炉低氮稳燃研究,E-mail:zxbzylzdy@126.com

Testing and Numerical Simulation on the Abrasion of SCR Catalysts

YAN Junfu, ZHAO Xuebin   

  1. Shanxi Xingneng Power Co., Ltd., Taiyuan 030206, China
  • Received:2018-08-20 Revised:2018-10-20 Online:2019-05-05 Published:2019-05-14

摘要: 高灰型布置的SCR脱硝系统其催化剂运行环境恶劣,烟气流速、飞灰颗粒及其粒径大小等客观因素对催化剂均会造成磨损。为研究烟气流速、飞灰粒径、飞灰质量浓度以及烟气入射角等对催化剂磨损造成的影响,采用日趋成熟的CFD数值模拟软件对不同工况时的SCR脱硝催化剂磨损情况进行研究,并且通过自建的冷态试验台进行了验证。研究结果表明,脱硝催化剂的磨损与上述4种影响因素均有很大关系,其中飞灰质量浓度、烟气入射角的变化对催化剂的磨损率影响较大,因此在实际运行中应增设导流板,避免因入射角和飞灰质量浓度的不均匀性导致催化剂磨损,另外还应选择合理的烟气流速以减小磨损,保证SCR系统的安全稳定运行。

关键词: SCR脱硝系统, 脱硝催化剂, 催化剂磨损, 数值模拟, 飞灰, 烟气入射角

Abstract: Since the high-ash-content type SCR denitration system is operated under very rough conditions, the factors such as flue gas flow rate and fly ash particles even the particle diameter will contribute to the wearing away of the catalyst. Through the application of mature CFD numerical simulation software, the abrasion of SCR denitration catalyst was studied under different operating conditions regarding the impacts of flue gas velocity, ash particle diameter, fly ash mass concentration and angle of incidence, then verified through the cold test bench established by ourselves. The results show that the abrasion of the denitration catalyst is closely related to the above four influencing factors, of which the fly ash mass concentration and the angle of incidence of the flue gas make significant impacts on the wear of the catalyst. Therefore, in the actual operation, the deflector baffles should be added to alleviate the abrasions from the non-uniformity of the incident angle or the unevenness of the fly ash mass concentrations. In addition a reasonable flue gas flow rate should be set to reduce wear and tear to ensure the secure operation of the system.

Key words: SCR denitration system, denitration catalyst, catalyst wear, numerical simulation, fly ash, smoke incident angle

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