中国电力 ›› 2019, Vol. 52 ›› Issue (4): 161-166.DOI: 10.11930/j.issn.1004-9649.201805230

• 节能与环保 • 上一篇    下一篇

燃煤电厂痕量元素协同脱除及排放

车凯1, 郑庆宇2, 韩忠阁1, 陈崇明1, 郁金星1   

  1. 1. 国网河北省电力有限公司电力科学研究院, 河北 石家庄 050021;
    2. 北方工程设计研究院有限公司, 河北 石家庄 050011
  • 收稿日期:2018-06-04 修回日期:2018-08-03 出版日期:2019-04-05 发布日期:2019-04-16
  • 作者简介:车凯(1985-),男,硕士,高级工程师,从事大气污染防控研究,E-mail:chekai311@163.com;郑庆宇(1986-),女,硕士,工程师,从事燃煤电站污染防控研究,E-mail:kaoyanqingyu@163.com

Research on Co-removal and Emission of Trace Elements in the Coal-Fired Power Plant

CHE Kai1, ZHENG Qingyu2, HAN Zhongge1, CHEN Chongming1, YU Jinxing1   

  1. 1. State Grid Hebei Electric Power Research Institute, Shijiazhuang 050021, China;
    2. Norendar International Co., Ltd., Shijiazhuang 050011, China
  • Received:2018-06-04 Revised:2018-08-03 Online:2019-04-05 Published:2019-04-16

摘要: 为了研究痕量元素在电厂排放物中的分布、富集以及常规污染物净化设施(脱硝装置(SCR)、电除尘器(ESP)、湿法烟气脱硫装置(WFGD)、湿式电除尘器(WESP))对痕量元素的协同脱除效果,采用美国环境保护署(USEPA)方法29,对某350 MW典型燃煤机组烟气及各污染物净化设施排放物中11种痕量元素(Be、Cr、Mn、Co、Ni、As、Se、Cd、Sb、Pb、Hg)浓度进行了测试。结果表明,煤粉燃烧后释放的痕量元素主要富集在ESP飞灰和石膏中,而在炉渣和烟囱入口烟气中分布较少;富集在ESP飞灰和石膏中的痕量元素分别占痕量元素排放总量的54.51%~97.58%和1.61%~38.08%;常规污染物净化设施对烟气中痕量元素的综合脱除效率为91.98%~99.98%,烟囱入口排放的痕量元素质量浓度为0.02~9.23 μg/m3,其中Mn、As、Se、Pb等元素质量浓度高于美国EPA颁布的火电厂环保标准中新建燃煤机组排放限值。

关键词: 燃煤电厂, 痕量元素, 污染物净化设施, 协同脱除, 减排控制

Abstract: In order to study the distribution and enrichment of the trace elements in the emissions from power plants and the synergistic removal of the trace elements from conventional pollutant purification facilities(SCR, ESP, WFGD, WESP), the concentration of the trace elements (Be, Cr, Mn, Co, Ni, As, Se, Cd, Sb, Pb, Hg) in the emissions of smoke and air pollutant control devices are tested by using US EPA Method 29 in a 350 MW coal-fired power unit. The results show that the trace elements that are mainly distributed in the fly ash and the gypsum takes 54.51%~97.58% and 1.61%~38.08% respectively of the total amount of emitted trace elements, while much less are distributed in the bottom ash and the chimney inlet flue gas. The overall removal rate through air pollutant control devices is 91.98%~99.98%. The concentration of trace elements in the stack is 0.02~9.23 μg/m3, and the concentration values of Mn, As, Se, Pb concentrations are much higher than the ones that are required for the new coal-fired unit trace elements emission quality standards issued by EPA.

Key words: coal-fired power plant, trace elements, air pollutant control devices, co-removal, emission reduction control

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