供氢体应用于碳捕集与资源化领域的前景分析

doi:10.11930/j.issn.1004-9649.201703022

中国电力 ›› 2018, Vol. 51 ›› Issue (6): 155-159.DOI: 10.11930/j.issn.1004-9649.201703022

供氢体应用于碳捕集与资源化领域的前景分析

赵毅¹, 王添颢¹, 王涵¹, 王晓慧¹, 郝思琪², 王永斌¹

1. 华北电力大学环境科学与工程学院, 河北保定 071003;
2. 承德石油高等专科学校化学工程系, 河北承德 067000

收稿日期:2017-03-30 修回日期:2018-02-08 出版日期:2018-06-05 发布日期:2018-06-12
通讯作者: 王添颢,18701131941,E-mail:ncepuwth@126.com
作者简介:赵毅(1956-),男,博士生导师,教授,从事火电厂环境保护方面的研究,E-mail:zhaoyi9515@163.com
基金资助:
国家重点研发计划资助项目（2016YFC0203705，2017YFC0210603）；中央高校基本科研业务费专项资金资助项目（2015ZZD07，2017XS131）；国家科技支撑计划资助项目（2014BAC23B04-06）；中国公益事业专项科研基金资助项目（201309018）；北京重大科技成果转化项目（Z151100002815012）；国家自然科学基金资助项目（51708213）。

Prospects for the Application of Hydrogen Donors in Carbon Capture and Resource Utilization

ZHAO Yi¹, WANG Tianhao¹, WANG Han¹, WANG Xiaohui¹, HAO Siqi², WANG Yongbin¹

1. School of Environmental Science and Engineering, North China Electric Power University, Baoding 071003, China;
2. Department of Chemical Engineering, Chengde Petroleum College, Chengde 067000, China

Received:2017-03-30 Revised:2018-02-08 Online:2018-06-05 Published:2018-06-12
Supported by:
This work is supported by National Key Research and Development Plan (No.2016YFC0203705, No.2017YFC0210603); Fundamental Research Funds for the Central Universities (No.2015ZZD07, No.2017XS131); National Science-technology Support Plan of China (No.2014BAC23B04-06); Special Scientific Research Fund of Public Welfare Profession of China (No.201309018); Beijing Major Scientific and Technological Achievement Transformation Project of China (No.Z151100002815012) and National Natural Science Foundation of China (No.51708213).

摘要/Abstract

摘要： 二氧化碳（CO₂）的大量排放已显著加剧温室效应和生态环境恶化。催化转移氢化法在CO₂资源化利用领域研究广泛且技术成熟。从以气态氢为主要还原剂催化氢化CO₂工艺的研究现状、供氢体还原特性及其目前应用进展等角度展开综述，并就上述研究中存在的优势和不足提出见解，建议未来供氢体应用于碳捕集与资源化领域可能的研究方向，旨在为推动CO₂资源化利用研究的长足发展提供借鉴。

关键词: 燃煤发电, 二氧化碳, 气态氢, 供氢体, 资源化利用

Abstract: Large amount of carbon dioxide (CO₂) emissions have significantly exacerbated the greenhouse effect and the deterioration of the ecological environment. The catalytic transfer hydrogenation method has been extensively studied and technically mature in the field of CO₂ resource utilization. In this paper, the study of the CO₂ catalytic hydrogenation technology with gaseous hydrogen as the main reductant, the reduction characteristics of the hydrogen donors, and current applications are summarized. The pros and cons of the studies are presented as well. Finally, suggestions are given for future research on the application of the hydrogen donors in the field of carbon capture and resource utilization, aiming to provide references for the future development of CO₂ resource utilization.

Key words: coal-fired power generation, carbon dioxide, gaseous hydrogen, hydrogen donor, resource utilization

中图分类号:

赵毅, 王添颢, 王涵, 王晓慧, 郝思琪, 王永斌. 供氢体应用于碳捕集与资源化领域的前景分析[J]. 中国电力, 2018, 51(6): 155-159.

ZHAO Yi, WANG Tianhao, WANG Han, WANG Xiaohui, HAO Siqi, WANG Yongbin. Prospects for the Application of Hydrogen Donors in Carbon Capture and Resource Utilization[J]. Electric Power, 2018, 51(6): 155-159.

导出引用管理器 EndNote|Ris|BibTeX

链接本文: https://www.electricpower.com.cn/CN/10.11930/j.issn.1004-9649.201703022

https://www.electricpower.com.cn/CN/Y2018/V51/I6/155

参考文献

[1] 赵毅, 刘威, 张自丽, 等. 光催化还原二氧化碳影响因素分析[J]. 中国电力, 2013, 46(1):90-95.ZHAO Yi, LIU Wei, ZHANG Zili, et al. Analysis of factors affecting photocatalytic reduction of CO₂[J]. Electric Power, 2013, 46(1):90-95.
[2] LEUNG D Y C, CARAMANNA G, MAROTO-VALER M M. An overview of current status of carbon dioxide capture and storage technologies[J]. Renewable and Sustainable Energy Reviews, 2014, 39(39):426-443.
[3] CHOI Y H, JANG Y J, PARK H, et al. Carbon dioxide fischer-tropsch synthesis:A new path to carbon-neutral fuels[J]. Applied Catalysis B:Environmental, 2017, 202:605-610.
[4] LEINO E, KUMAR N, MÄKI-ARVELA P, et al. Synthesis and characterization of ceria-supported catalysts for carbon dioxide transformation to diethyl carbonate[J]. Catalysis Today, 2018(306):128-137.
[5] GANESH I. Electrochemical conversion of carbon dioxide into renewable fuel chemicals - The role of nanomaterials and the commercialization[J]. Renewable and Sustainable Energy Reviews, 2016, 59:1269-1297.
[6] KIM H-Y, CHOI I, AHN S H, et al. Analysis on the effect of operating conditions on electrochemical conversion of carbon dioxide to formic acid[J]. International Journal of Hydrogen Energy, 2014, 39(29):16506-16512.
[7] SUN Y, LI G, XU J, et al. Visible-light photocatalytic reduction of carbon dioxide over SnS2[J]. Materials Letters, 2016, 174:238-241.
[8] RELI M, KOBIELUSZ M, MATěJOVÁ L, et al. TiO₂ processed by pressurized hot solvents as a novel photocatalyst for photocatalytic reduction of carbon dioxide[J]. Applied Surface Science, 2017, 391, Part B:282-287.
[9] ZHAO K, WANG W, LI Z. Highly efficient Ni/ZrO₂ catalysts prepared via combustion method for CO₂ methanation[J]. Journal of CO₂ Utilization, 2016, 16:236-244.
[10] XIAO S, ZHANG Y, GAO P, et al. Highly efficient Cu-based catalysts via hydrotalcite-like precursors for CO₂ hydrogenation to methanol[J]. Catalysis Today, 2017(281):327-336.
[11] GARBARINO G, BELLOTTI D, RIANI P, et al. Methanation of carbon dioxide on Ru/Al₂O₃ and Ni/Al₂O₃ catalysts at atmospheric pressure:Catalysts activation, behaviour and stability[J]. International Journal of Hydrogen Energy, 2015, 40(30):9171-9182.
[12] REDDY KANNAPU H P, MULLEN C A, ELKASABI Y, et al. Catalytic transfer hydrogenation for stabilization of bio-oil oxygenates:Reduction of p-cresol and furfural over bimetallic Ni-Cu catalysts using isopropanol[J]. Fuel Processing Technology, 2015, 137:220-228.
[13] SIVCEV V P, VOLCHO K P, SALAKHUTDINOV N F, et al. Unique shortening of carbon chain during reduction of aliphatic nitro compounds to amines in the presence of supercritical isopropanol on alumina[J]. The Journal of Supercritical Fluids, 2015, 103:101-104.
[14] KALWAR N H, SIRAJUDDIN, SHERAZI S T H, et al. Synthesis of l-methionine stabilized nickel nanowires and their application for catalytic oxidative transfer hydrogenation of isopropanol[J]. Applied Catalysis A:General, 2011, 400(1-2):215-220.
[15] Nixon T D, Whittlesey M K, Williams J M J. Ruthenium-catalysed transfer hydrogenation reactions with dimethylamine borane[J]. Tetrahedron Letters, 2011, 52(49):6652-6654.
[16] YURDERI M, BULUT A, ZAHMAKIRAN M, et al. Ruthenium(0) nanoparticles stabilized by metal-organic framework (ZIF-8):Highly efficient catalyst for the dehydrogenation of dimethylamine-borane and transfer hydrogenation of unsaturated hydrocarbons using dimethylamine-borane as hydrogen source[J]. Applied Catalysis B:Environmental, 2014, 160-161(1):534-541.
[17] DEMIRCI U B. Ammonia borane, a material with exceptional properties for chemical hydrogen storage[J]. International Journal of Hydrogen Energy, 2017, 42(15):9978-10013.
[18] MANNA J, AKBAYRAK S, ZKAR S. Palladium(0) nanoparticles supported on polydopamine coated CoFe₂O₄ as highly active, magnetically isolable and reusable catalyst for hydrogen generation from the hydrolysis of ammonia borane[J]. Applied Catalysis B:Environmental, 2017, 208:104-115.
[19] YANG X J, LI L L, SANG W L, et al. Boron nitride supported Ni nanoparticles as catalysts for hydrogen generation from hydrolysis of ammonia borane[J]. Journal of Alloys and Compounds, 2017, 693:642-649.
[20] PICASSO C V, SAFIN D A, DOVGALIUK I, et al. Reduction of CO₂ with KBH₄ in solvent-free conditions[J]. International Journal of Hydrogen Energy, 2016, 41(32):14377-14386.
[21] FLETCHER C, JIANG Y, AMAL R. Production of formic acid from CO₂ reduction by means of potassium borohydride at ambient conditions[J]. Chemical Engineering Science, 2015, 137:301-307.
[22] ZHAO Y, ZHANG Z. Thermodynamic properties of CO₂ conversion by sodium borohydride[J]. Chemical Engineering & Technology, 2015, 38(1):110-116.
[23] ZHAO Y, ZHANG Z, QIAN X, et al. Properties of carbon dioxide absorption and reduction by sodium borohydride under atmospheric pressure[J]. Fuel, 2015, 142:1-8.
[24] ZHAO Y, ZHANG Z, WANG H, et al. Absorption of carbon dioxide by hydrogen donor under atmospheric pressure[J]. Renewable and Sustainable Energy Reviews, 2016, 64:84-90.
[25] ZHAO Y, ZHANG Z, ZHAO X, et al. Catalytic reduction of carbon dioxide by nickel-based catalyst under atmospheric pressure[J]. Chemical Engineering Journal, 2016, 297:11-18.

供氢体应用于碳捕集与资源化领域的前景分析

Prospects for the Application of Hydrogen Donors in Carbon Capture and Resource Utilization

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

[1]	刘含笑, 单思珂, 魏书洲, 于立元, 王帅, 刘美玲, 崔盈. 基于生命周期法的煤电碳足迹评估[J]. 中国电力, 2024, 57(7): 227-237.
[2]	陈欢乐, 归一数, 陈伟, 王阳, 卢宏林, 明磊. 基于加热器切除的深度调频控制技术研究与实施[J]. 中国电力, 2021, 54(3): 168-176.
[3]	陆骏超, 陶雷行, 岳春妹, 陈睿, 刘志超, 王妍艳, 郑方栋, 万迪. 燃煤发电厂用水水平现状与展望[J]. 中国电力, 2020, 53(3): 139-146.
[4]	王霂晗, 朱林, 张晶杰, 杨帆. 欧盟火电厂二氧化碳排放在线监测系统质量保证体系对中国的启示[J]. 中国电力, 2020, 53(3): 154-158,176.
[5]	张金生. 太阳能塔式聚光集热系统与燃煤发电耦合设计[J]. 中国电力, 2020, 53(2): 150-155.
[6]	伦涛, 鄂志君, 张利, 王鑫, 赵永亮, 严俊杰. 燃煤机组不同灵活性调节方案参与一次调频过程的经济性分析[J]. 中国电力, 2019, 52(8): 164-172.
[7]	吕培鑫, 庞力平, 李明, 段立强, 杨勇平. 太阳能辅助燃煤发电系统变工况动态特性分析[J]. 中国电力, 2019, 52(7): 108-116.
[8]	王天堃. 基于神经网络模型及预测控制DMC的火电机组脱硝控制策略[J]. 中国电力, 2019, 52(12): 140-145.
[9]	牟春华, 吕凯, 许朋江, 孙大伟, 兀鹏越, 马汀山, 居文平, 李冬泉. 辅机统调动力源系统在某660 MW机组的应用[J]. 中国电力, 2018, 51(9): 65-72.
[10]	邓攀, 王亚军. BEST技术用于超超临界二次再热机组的可行性分析[J]. 中国电力, 2018, 51(7): 84-89.
[11]	张仁锋, 苏燊燊, 马继军, 谢永平, 孙希进, 韩建华. 烟塔合一的环境影响实证研究[J]. 中国电力, 2018, 51(7): 162-169.
[12]	翁卫国, 孙建国, 李钦武, 周灿, 蒋善行. 脱硫废水零排放系统关键参数数值模拟研究[J]. 中国电力, 2018, 51(6): 42-47.
[13]	史晓宏, 刘毅, 仲兆平, 张锴, 赵凯. 富氧燃烧气氛石灰石溶解特性研究[J]. 中国电力, 2018, 51(3): 155-162.
[14]	李泉, 尹峰, 张政委, 侯国莲, 罗志浩. 乘数型主蒸汽温度预测函数控制研究及应用[J]. 中国电力, 2017, 50(8): 37-40.
[15]	刘庆威, 果志明, 陆叶, 任立立, 杜大全. 旋流锅炉低氮燃烧器改造后运行情况分析[J]. 中国电力, 2017, 50(8): 63-67.

模态框（Modal）标题

供氢体应用于碳捕集与资源化领域的前景分析

Prospects for the Application of Hydrogen Donors in Carbon Capture and Resource Utilization

RichHTML

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics