燃煤电厂湿法烟气脱硫废水处理技术研究进展

doi:10.11930/j.issn.1004-9649.201706196

中国电力 ›› 2018, Vol. 51 ›› Issue (12): 175-179.DOI: 10.11930/j.issn.1004-9649.201706196

燃煤电厂湿法烟气脱硫废水处理技术研究进展

聂向欣¹, 郑宗明¹, 崔孝洋¹, 陆强¹, 董长青¹, 赵锦²

1. 华北电力大学生物质发电成套设备国家工程实验室, 北京 102206;
2. 国网节能服务有限公司, 北京 100052

收稿日期:2017-06-29 修回日期:2017-12-20 出版日期:2018-12-05 发布日期:2018-12-13
作者简介:聂向欣(1991-),男,硕士研究生,从事能源清洁高效利用方面的研究,E-mail:xiangxinnie@126.com;郑宗明(1974-),男,副教授,从事新能源开发利用与节能环保方面的研究,E-mail:zmzheng@ncepu.edu.cn

Research Progress on the Treatment Technologies of Wet Flue Gas Desulfurization Wastewater in Coal-fired Power Plants

NIE Xiangxin¹, ZHENG Zongming¹, CUI Xiaoyang¹, LU Qiang¹, DONG Changqing¹, ZHAO Jin²

1. National Engineering Laboratory for Biomass Power Generation Equipment, North China Electric Power University, Beijing 102206, China;
2. State Grid Energy Saving Service Co., Ltd., Beijing 100052, China

Received:2017-06-29 Revised:2017-12-20 Online:2018-12-05 Published:2018-12-13

摘要/Abstract

摘要： 脱硫废水处理是燃煤电厂深度节水的难点之一。在讨论石灰石—石膏湿法脱硫废水特点的同时，介绍了包括三联箱处理法、膜处理法、热处理法及电解处理法在内的国内外典型脱硫废水处理技术，指出高效规模化的脱硫废水处理技术应是包括预处理、浓缩和资源化等过程的系统集成技术。预处理对溶解态钙镁离子、胶体颗粒物和无机垢成分的脱除起着至关重要的作用，可以避免浓缩及资源化过程中因滤膜极化、滤膜污染、换热设备结垢、电解槽电阻增大等现象造成的膜渗透通量下降、传热及电解效率降低等问题。建议从降浊和软化的角度强化三联箱法的预处理水平，为后续零排放处理创造条件。

关键词: 燃煤电厂, 深度节水, 脱硫废水, 预处理, 三联箱法, 零排放

Abstract: The treatment of desulphurization wastewater is one of the challenges hindering further water saving in coal-fired power plants. In this paper, the typical treatment technologies, including triple box treatment, membrane-based treatment, thermal-based treatment and electrolytic treatment are introduced while the characteristics of limestone/gypsum wet desulphurization wastewater are discussed. The future treatment technologies of desulfurization wastewater should integrate pretreatment, concentration and resource utilization process etc. In particular, pretreatment plays an indispensible role in the removal of dissolved calcium and magnesium ions, colloidal particles and inorganic scale components. Specifically, problems such as decrease of permeation flux, decline of heat transfer efficiency and electrolytic efficiency due to polarization of membrane, fouling of membrane, scaling of heat transfer equipment or resistance increase of electrolytic bath can be avoided in the process of concentration and resource utilization by pretreatment. In order to create conditions for follow-up zero discharge treatment, it is suggested that the pretreatment level of triple box treatment should be strengthened from the view of turbidity reduction and water softening.

Key words: coal-fired power plants, deep water saving, desulphurization wastewater, pretreatment, triple box treatment, zero discharge

中图分类号:

X703
TM621.9

聂向欣, 郑宗明, 崔孝洋, 陆强, 董长青, 赵锦. 燃煤电厂湿法烟气脱硫废水处理技术研究进展[J]. 中国电力, 2018, 51(12): 175-179.

NIE Xiangxin, ZHENG Zongming, CUI Xiaoyang, LU Qiang, DONG Changqing, ZHAO Jin. Research Progress on the Treatment Technologies of Wet Flue Gas Desulfurization Wastewater in Coal-fired Power Plants[J]. Electric Power, 2018, 51(12): 175-179.

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https://www.electricpower.com.cn/CN/Y2018/V51/I12/175

参考文献 27

[1]	张江涛, 曹红梅, 董娟, 等. 火电厂废水零排放技术路线比较及影响因素分析[J]. 中国电力, 2017, 50(6):120-124. ZHANG Jiangtao, CAO Hongmei, DONG Juan, et al. Comparison on the technical routes of zero liquid discharge of fossil-fired power plants and analysis on the influencing factors[J]. Electric Power, 2017, 50(6):120-124.
[2]	HIGGINS T, GIVENS S, SANDY T, et al. FGD wastewater treatment still has a way to go[J]. Power Engineering-Barrington then Tulsa, 2008, 112(1):68-70.
[3]	HIGGINS T E, SANDY A T, GIVENS S W, et al. Flue gas desulfurization wastewater treatment primer[J]. Power, 2009, 153(3):40-43.
[4]	兰春锋, 苏清发, 吴慕正. 美国电厂石灰石-石膏湿法脱硫废水硒污染治理及对中国的启示[J]. 电力科技与环保, 2013, 29(1):59-62. LAN Chunfeng, SU Qingfa, WU Muzheng. The US power plant wet limestone FGD selenium wastewater treatment control and its implications for China[J]. Electric Power Technology and Environmental Protection, 2013, 29(1):59-62.
[5]	张胜寒, 孙晨皓, 陈玉强, 等. 燃煤电厂脱硫废水中硒元素脱除技术研究进展[J]. 化工进展, 2017, 36(4):1460-1469. ZHANG Shenghan, SUN Chenhao, CHEN Yuqiang, et al. Research progress on selenium removal of FGD wastewater from coal-fired power plants[J]. Chemical Industry and Engineering Progress, 2017, 36(4):1460-1469.
[6]	CÓRDOBA P. Partitioning and speciation of selenium in wet limestone flue gas desulphurisation (FGD) systems:a review[J]. Fuel, 2017, 202:184-195.
[7]	胡石, 丁邵峰, 樊兆世. 燃煤电厂脱硫废水零排放工艺研究[J]. 洁净煤技术, 2015, 21(2):129-133. HU Shi, DING Shaofeng, FAN Zhaoshi. Zero release technology of desulfurization waste water in coal -fired power plant[J]. Clean Coal Technology, 2015, 21(2):129-133.
[8]	连坤宙, 陈景硕, 刘朝霞, 等. 火电厂脱硫废水微滤、反渗透膜法深度处理试验研究[J]. 中国电力, 2016, 49(2):148-152. LIAN Kunzhou, CHEN Jingshuo, LIU Zhaoxia, et al. Experimental study on the reduction treatment of desulfurization wastewater in power plants by membrane[J]. Electric Power, 2016, 49(2):148-152.
[9]	SHRIVASTAVA B K. Efficient management of reverse osmosis system in water treatment plant[J]. International Journal of Chemical Sciences, 2009, 7(3):2047-2055.
[10]	胡小武. 高效反渗透废水处理工艺在电厂废水零排放中的应用[J]. 神华科技, 2011, 9(5):92-96. HU Xiaowu. The application of high-efficient reverse osmosis wastewater treatment in the zero-emission of power plan[J]. Shenhua Science and Technology, 2011, 9(5):92-96.
[11]	吴优福, 刘捷, 海玉琰, 等. 超超临界1000 MW机组脱硫废水零排放技术[J]. 热力发电, 2017, 46(5):108-114. WU Youfu, LIU Jie, HAI Yuyan, et al. Discussions on zero-discharge technology of desulfurization wastewater for ultra supercritical units[J]. Thermal Power Generation, 2017, 46(5):108-114.
[12]	LUTCHMIAH K, VERLIEFDE A R, ROEST K, et al. Forward osmosis for application in wastewater treatment:a review[J]. Water Research, 2014, 58(3):179-197.
[13]	CATH T Y, CHILDRESS A E, ELIMELECH M. Forward osmosis:principles, applications and recent developments[J]. Journal of Membrane Science, 2006, 281(1/2):70-87.
[14]	ZOU S, GU Y, XIAO D. The role of physical and chemical parameters on forward osmosis membrane fouling during algae separation[J]. Journal of Membrane Science, 2011, 366(1/2):356-362.
[15]	HUSNAIN T, MI B, TIFFAT R. A combined forward osmosis and membrane distillation system for sidestream treatment[J]. Journal of Water Resource and Protection, 2015, 7(14):1111-1120.
[16]	李竹梅, 王建强, 李永和, 等. 膜蒸馏技术在电厂脱硫废水处理领域的中试应用[C]//国际脱盐大会暨全国冶金节水与废水利用技术研讨会. 青岛, 2016.
[17]	PANGARKAR B L, SANE M G, GUDDAD M. Reverse osmosis and membrane distillation for desalination of groundwater:A review[J]. Isrn Materials Science, 2011:1-9.
[18]	WARSINGER D M, SWAMINATHAN J, GUILLEN-BURRIEZA E, et al. Scaling and fouling in membrane distillation for desalination applications:A review[J]. Desalination, 2015, 356(6):294-313.
[19]	贾文. 海水淡化技术及市场[J]. 东方电气评论, 2009, 23(3):35-42. JIA Wen. Seawater desalination technology and market[J]. Dongfang Electric Review, 2009, 23(3):35-42.
[20]	Al-RAWAJFEH A E, IHM S, VARSHENY H, et al. Scale formation model for high top brine temperature multi-stage flash (MSF)desalination plants[J]. Desalination, 2014, 350:53-60.
[21]	香川晴治, 神山直行, 牛久哲, 等. 脱硫装置における無排水化技術の開発[J]. 三菱重工技報, 2015, 52(4):41-44
[22]	毛进, 张志国, 连坤宙, 等. 火电厂脱硫废水资源化回用处理工艺研究[J]. 水处理技术, 2017, 43(6):41-44. MAO Jin, ZHANG Zhiguo, LIAN Kunzhou, et al. Study on the resource recycling and reuse treatment of desulfurization wastewater in power plant[J]. Technology of Water Treatment, 2017, 43(6):41-44.
[23]	NIELSEN P B, CHRISTENSEN T C, VENDRUP M. Continous removal of heavy metals from FGD wastewater in a fluidized bed without sludge generation[J]. Water Science and Technology, 1997, 36(2/3):391-397.
[24]	HUANG Y H, PEDDI P, TANG C, et al. Hybrid zero-valent iron process for removing heavy metals and nitrate from flue-gas-desulfurization wastewater[J]. Separation and Purification Technology, 2013, 118:690-698.
[25]	GUAN B, NI W, WU Z, et al. Removal of Mn(Ⅱ) and Zn(Ⅱ) ions from flue gas desulfurization wastewater with water-soluble chitosan[J]. Separation and Purification Technology, 2009, 65:269-274.
[26]	LIU S, YE X, HE K, et al. Simultaneous removal of Ni (Ⅱ) and fluoride from a real flue gas desulfurization wastewater by electrocoagulation using Fe/C/Al electrode[J]. Journal of Water Reuse & Desalination, 2017, 7(3):288-297.
[27]	PAKZADEH B, RENEW J, WOS J. Coal-fired power plant flue gas desulfurization wastewater Treatment[J]. Proceedings of the Water Environment Federation, 2014(12):2417-2428.

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Research Progress on the Treatment Technologies of Wet Flue Gas Desulfurization Wastewater in Coal-fired Power Plants

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燃煤电厂湿法烟气脱硫废水处理技术研究进展

Research Progress on the Treatment Technologies of Wet Flue Gas Desulfurization Wastewater in Coal-fired Power Plants

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