核电站二回路乙醇胺与氨复合应用可行性研究

doi:10.11930/j.issn.1004-9649.201810041

中国电力 ›› 2019, Vol. 52 ›› Issue (4): 127-132.DOI: 10.11930/j.issn.1004-9649.201810041

核电站二回路乙醇胺与氨复合应用可行性研究

赵永福, 姜峨, 龚宾, 温菊花, 唐敏, 银朝晖, 何艳春

中国核动力研究设计院, 四川成都 610213

收稿日期:2018-10-16 修回日期:2018-12-27 出版日期:2019-04-05 发布日期:2019-04-16
作者简介:赵永福(1987-),男,助理研究员,从事核反应堆水化学及材料腐蚀研究工作,E-mail:zhaoyongfu0127@126.com
基金资助:
国家科技重大专项资助项目（2011ZX06004-017）。

Feasibility Study on Combined Application of Ethanolamine and Ammonia in the Secondary Circuit of Nuclear Power Plant

ZHAO Yongfu, JIANG E, GONG Bin, WEN Juhua, TANG Min, YIN Zhaohui, HE Yanchun

Nuclear Power Institute of China, Chengdu 610213, China

Received:2018-10-16 Revised:2018-12-27 Online:2019-04-05 Published:2019-04-16
Supported by:
This work is supported by National Science and Technology Major Project (No.2011ZX06004-017).

摘要/Abstract

摘要： 为进一步优化核电站二回路水化学工况，降低二回路水化学运行成本，分析了核电站二回路采用单一碱化剂存在的问题，提出了乙醇胺和氨复合应用的对策和基本依据。采用Chemworks软件，计算乙醇胺和氨不同配比复合应用于典型核电站二回路系统时不同部位工质的碱化剂浓度及pH值，筛选出了最佳乙醇胺质量分数（w_ETA）和氨质量分数（w_NH₃）配比及其范围，并通过高压釜试验验证了理论计算结果。研究表明：当核电站二回路给水中w_ETA：w_NH₃≈4∶1、2×10^-6≤w_ETA≤4×10^-6、0.5×10^-6≤w_NH₃≤1×10^-6时，应用效果较好。

关键词: 核电站, 二回路, 水化学工况, 乙醇胺, 氨, 碱化剂复合应用, 碱化剂配比

Abstract: The problems from the usage of single alkalinity treatment were analyzed and then the countermeasures and basic standards of combined application of ethanolamine (ETA) and ammonia in the secondary circuit of nuclear power plant (NPP) were put forward in order to further optimize water chemistry condition and reduce chemical operation cost. With various combination ratios of ethanolamine and ammonia, the alkalinity concentration and pH values at different parts of secondary circuit of a typical nuclear power plant were calculated by CHEMWORKS. The optimum concentration ratio and range of ethanolamine and ammonia were filtered and verified by theoretical calculation and autoclave tests. The results show that satisfactory outcome can be attained in practice when the concentrations of ethanolamine and ammonia in the feed-water of secondary circuit meet the following requirements: w_ETA:w_NH3≈4:1, 2×10^-6≤w_ETA≤4×10^-6, 0.5×10^-6≤w_NH₃≤1×10^-6.

Key words: nuclear power plant, secondary circuit, water chemistry condition, ETA, ammonia, combined application of alkalinity, concentration ratio of alkalinity

中图分类号:

TM623.7

赵永福, 姜峨, 龚宾, 温菊花, 唐敏, 银朝晖, 何艳春. 核电站二回路乙醇胺与氨复合应用可行性研究[J]. 中国电力, 2019, 52(4): 127-132.

ZHAO Yongfu, JIANG E, GONG Bin, WEN Juhua, TANG Min, YIN Zhaohui, HE Yanchun. Feasibility Study on Combined Application of Ethanolamine and Ammonia in the Secondary Circuit of Nuclear Power Plant[J]. Electric Power, 2019, 52(4): 127-132.

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https://www.electricpower.com.cn/CN/Y2019/V52/I4/127

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核电站二回路乙醇胺与氨复合应用可行性研究

Feasibility Study on Combined Application of Ethanolamine and Ammonia in the Secondary Circuit of Nuclear Power Plant

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核电站二回路乙醇胺与氨复合应用可行性研究

Feasibility Study on Combined Application of Ethanolamine and Ammonia in the Secondary Circuit of Nuclear Power Plant

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